Dos Estructuras Inesperadas De Complejos Metálicos Del Grupo Del Platino Con 1,2-DIHIDRO-2,5- DIFENIL-3H-1,2,4-TRIAZOL-TIONA H

Palladium (II) and platinum (II) complexes 5 and 6 were synthesized using 1,2-dihydro-2,5- diphenyl-3H-1,2,4-triazole-3-thion 3 as a ligand from an isomeric mixture of 3 and 4. The unexpected structures of 5 and 6 were investigated by mass spectra, IR (DRIFT), and ESCA measurements as well as crystal structure determinations. The palladium (II) complex is tetranuclear with two groups of Pd