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A synthetic dinuclear copper (II) hydrolase and its potential as antitumoral: Cytotoxicity, cellular uptake, and DNA cleavage

July 17, 2017 | Autor: Elene Pereira-Maia | Categoría: Inorganic Chemistry, Kinetics, Inorganic, Cytotoxicity, Humans, Copper, Mice, Female, Animals, Male, Cytotoxic Activity, DNA binding, Neoplasms, DNA Cleavage, Inorganic Biochemistry, Aqueous Solution, Organometallic Compounds, Cell Survival, Kinetic Parameter, Antineoplastic Agents, Plasmid DNA, Cell Growth, Copper, Mice, Female, Animals, Male, Cytotoxic Activity, DNA binding, Neoplasms, DNA Cleavage, Inorganic Biochemistry, Aqueous Solution, Organometallic Compounds, Cell Survival, Kinetic Parameter, Antineoplastic Agents, Plasmid DNA, Cell Growth
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We have studied the protonation equilibria of a dicopper(II) complex [Cu 2 (μ-OH)(C 21 H 33 ON 6 )](ClO 4 ) 2 ·H 2 O, (1), in aqueous solution, its interactions with DNA, its cytotoxic activity, and its uptake in tumoral cells. C 21 H 33 ON 6 corresponds to the ligand ...
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